Synthesis, crystal structure and DFT study of a new copper (II) complex of N2O2 donor Schiff base ligand
Publication Date : 28/12/2015
One new Complex of formula [Cu(L)2] (1) has been prepared using tetradentate chelating ligand H2L, condensation product of 5-chloro-2-hydroxy acetophenone and 1,2-ethylenediamine and it has been characterized by means of elemental analysis, FT-IR,UV-VIS spectra, Mass spectroscopy study. Single crystal X-ray diffraction studies in solid-state revealing that environment of Cu(II) is four coordinated square-planar where Cu (II) coordinated by two imine nitrogen atoms and two phenoxide ions. The experimental electronic spectra and structure of complex (1) have been compared with the DFT calculated results.
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